Silica gel and calcium chloride have different ways to remove moisture from the surrounding environment. Silica gel does it by adsorption, which means that the water molecules adhere to the surface of the silica gel. The silica gel is a very porous component with a high number of voids that may contain water when needed.
Silica gel works well at unexceptional temperatures, while it may lose the capacity to adsorb at higher temperatures. At high temperatures, it might actually release moisture into the air.
Calcium Chloride has a much better performance when the relative humidity is high.
Calcium chloride increases its capacity to absorb water over time because the absorption process makes the moisture dissolve into the calcium chloride.
Due to the physical characteristics of the adsorption process, silica gel desiccants may be full up quickly. If that happens, their capacity to remove moisture remains low and very constant.
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